Hydroxylation of aryl- and alkylboronic acids/esters mediated by iodobenzene diacetate—an avenue for using organoboronic acids/esters as nucleophiles for hydroxylation reactions

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DC Field	Value	Language
dc.contributor.author	Chatterjee, N.
dc.contributor.author	Chowdhury, H.
dc.contributor.author	Sneh, K.
dc.contributor.author	Goswami, A.
dc.date.accessioned	2016-07-28T07:31:50Z
dc.date.available	2016-07-28T07:31:50Z
dc.date.issued	2016-07-28
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/119
dc.description.abstract	A metal free, mild, and highly efficient methodology for ipso-hydroxylation of diversely functionalized aryl- and alkylboronic acids/esters mediated by iodobenzene diacetate (DAIB) under ambient temperature has been developed. This protocol is also applicable to N-heterocyclic boronic acids and esters. In the course of understanding the mechanism of this protocol, it is anticipated that organoboronic acid/ester, even being an electron demanding moiety, is acting as a nucleophile in the presence of DAIB for the hydroxylation reaction.	en_US
dc.language.iso	en_US	en_US
dc.subject	Aliphatic alcohols	en_US
dc.subject	Aromatic alcohols	en_US
dc.subject	Hydroxylation	en_US
dc.subject	Hypervalent iodine	en_US
dc.subject	DAIB	en_US
dc.subject	Organoboronic acids/esters	en_US
dc.title	Hydroxylation of aryl- and alkylboronic acids/esters mediated by iodobenzene diacetate—an avenue for using organoboronic acids/esters as nucleophiles for hydroxylation reactions	en_US
dc.type	Article	en_US
Appears in Collections:	Year-2015

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