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dc.contributor.authorSarmah, B-
dc.contributor.authorSatpati, B.-
dc.contributor.authorSrivastava, R.-
dc.date.accessioned2019-01-02T15:20:30Z-
dc.date.available2019-01-02T15:20:30Z-
dc.date.issued2019-01-02-
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/1200-
dc.description.abstractThe direct, one-pot catalytic conversion of carbohydrates (especially sucrose and glucose) to 2,5- diformylfuran is a challenging task. The development of a bi-functional sustainable heterogeneous catalyst is crucial to achieve high selectivity for the desired product 2,5-diformylfuran in this direct conversion process. In this study, tandem, one-pot, two-step direct conversion of carbohydrates into 2,5-diformylfuran is reported using a Ru nanoparticle-supported H-beta catalyst. This carbohydrate conversion process is characterized by the abundance and low cost of reactants with no need for 5-hydroxymethylfurfural separation or purification. Molecular oxygen (1 atm) is used as an oxidant. No external oxidizing reagent is required to carry out this transformation. A combination of H-beta and Ru nanoparticles successfully affords the direct synthesis of 2,5-diformylfuran from carbohydrates via isomerization, dehydration, and successive selective oxidation under one-pot conditions. This one-pot tandem reaction protocol affords 2,5-diformylfuran with yields of 80% and 67% from fructose and sucrose, respectively. Moreover, the catalyst is easily recycled and reused without any loss of catalytic activity.en_US
dc.language.isoen_USen_US
dc.titleOne-pot tandem conversion of monosaccharides and disaccharides to 2,5-diformylfuran using a ru nanoparticle-supported h-beta catalysten_US
dc.typeArticleen_US
Appears in Collections:Year-2018

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