Please use this identifier to cite or link to this item: http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/1263
Title: Cu2+-driven metallo-supramolecular self-assembly and its application in sensing of hydroxyl ion
Authors: Kuwar, A.
Tayade, K.
Keshav, K.
Sahoo, S.K.
Mayank
Singh, N.
Keywords: Dinuclear copper complex
Single crystal XRD
ESR
Hydroxide sensor
Issue Date: 20-May-2019
Abstract: The dinuclear copper complex receptor (R) was synthesized using the ligands 4-(di-ethyl-amino)- 2-hydroxybenzaldehyde and benzo [d] thiazol-2-amine. The single crystal X-ray analysis of the homoleptic bis(μ-oxo)dicopper (II) complex indicated that the ligands are coordinated in an anticonfiguration to each other and have adopted a distorted square-pyramidal environment around the Cu2+ ion. The X-ray solid state structural analysis and DFT reveals no direct Cu…..Cu linkage within the complex. The anion recognition ability of the R was studied by UV–vis and fluorescence spectroscopic in acetonitrile. The results indicated that the new complex R displays a sturdy sympathy and selectivity for hydroxide ion.
URI: http://localhost:8080/xmlui/handle/123456789/1263
Appears in Collections:Year-2018

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