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DC Field | Value | Language |
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dc.contributor.author | Fegade, U. | |
dc.contributor.author | Singh, A. | |
dc.contributor.author | Chaitanya, G. K. | |
dc.contributor.author | Singh, N. | |
dc.contributor.author | Attarde, S. | |
dc.contributor.author | Kuwar, A. | |
dc.date.accessioned | 2016-08-10T10:46:01Z | |
dc.date.available | 2016-08-10T10:46:01Z | |
dc.date.issued | 2016-08-10 | |
dc.identifier.uri | http://localhost:8080/xmlui/handle/123456789/197 | |
dc.description.abstract | A new fluorescent receptor 1,1′-(4-methylbenzene-1,3-diyl)bis[3-(2-sulfanylphenyl)urea] (1) has been designed and synthesized. The receptor showed excellent selectivity for Fe3+ in DMSO/H2O (8:2, v/v) solvent system over other commonly coexistent metal ions. The binding constant (Ka) of receptor with Fe3+ was calculated to be 11,250 M−1, 12,970 M−1 and 12,970 M−1 using Benesi–Hildebrand, Scatchard and Connor plot, respectively. The experimental results have been further supported by the detailed DFT calculations. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | 1,1′-(4-Methylbenzene-1,3-diyl)bis[3-(2-sulfanylphenyl)urea] | en_US |
dc.subject | Fluorescence receptor | en_US |
dc.subject | Binding constant | en_US |
dc.subject | Metal ions | en_US |
dc.subject | Fe3+ sensor | en_US |
dc.title | Highly selective and sensitive receptor for Fe3+ probing | en_US |
dc.type | Article | en_US |
Appears in Collections: | Year-2014 |
Files in This Item:
File | Description | Size | Format | |
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1-s2.0-S1386142513013127-main.pdf | 1.42 MB | Adobe PDF | View/Open Request a copy |
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