Please use this identifier to cite or link to this item:
http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/3186
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choudhary, P. | - |
dc.contributor.author | Sen, A. | - |
dc.contributor.author | Kumar, A. | - |
dc.contributor.author | Dhingra, S. | - |
dc.contributor.author | Nagaraja, C. M. | - |
dc.contributor.author | Krishnan, V. | - |
dc.date.accessioned | 2021-11-16T17:40:03Z | - |
dc.date.available | 2021-11-16T17:40:03Z | - |
dc.date.issued | 2021-11-16 | - |
dc.identifier.uri | http://localhost:8080/xmlui/handle/123456789/3186 | - |
dc.description.abstract | Rational design and development of acid–base bifunctional heterogeneous catalysts for organic synthesis is a tough process. A highly efficient, non-toxic, metal-free, low-cost, acid–base bifunctional sulfonated graphitic carbon nitride (S-g-C3N4) catalyst has been developed. The as-synthesized S-g-C3N4 catalyst exhibits high catalytic potential towards Knoevenagel condensation and sequential tandem reactions. The as-synthesized catalyst was developed by sulfonation of graphitic carbon nitride (g-C3N4). The sulfonation leads to surface functionalization of –SO3H groups onto the catalyst surface. These –SO3H groups impart acidic nature to the S-g-C3N4 catalyst along with the preexisting basic nature of the catalyst due to the presence of N-containing moieties. These dual acid–base functionalities behave as active sites for the sequential catalytic reactions to occur. The S-g-C3N4 catalyst exhibits high turnover numbers (TON) and high yields in shorter reaction time at optimum conditions of temperature which demonstrates the high catalytic activity of the S-g-C3N4 nanosheets. The corresponding green metrics parameters were also calculated, in addition to demonstrating the excellent catalyst recyclability and reusability. The as-synthesized S-g-C3N4 catalyst provides a metal-free, sustainable and green approach for utilizing acid–base bifunctional catalysts for sequential organic synthesis. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Sulfonic acid functionalized graphitic carbon nitride as solid acid-base bifunctional catalyst for Knoevenagel condensation and multicomponent tandem reactions | en_US |
dc.type | Article | en_US |
Appears in Collections: | Year-2021 |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Full Text.pdf | 6.23 MB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.