Please use this identifier to cite or link to this item: http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/381
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSingha, A.
dc.contributor.authorSingh, A.
dc.contributor.authorSingh, N.
dc.contributor.authorJang, D. O.
dc.date.accessioned2016-11-17T08:56:43Z
dc.date.available2016-11-17T08:56:43Z
dc.date.issued2016-11-17
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/381
dc.description.abstractA benzothiazole-based receptor conjugated with an imidazolium cation, receptor N1, was synthesized. Receptor N1 is capable of selectively binding Hg(II) in the presence of other metal ions in water, with a large enhancement in fluorescence intensity at 380 nm via a PET mechanism. The resulting Hg(II) complex of receptor N1 showed a selective ratiometric response upon addition of Br− ions. The Hg(II) complex of receptor N1 was used to determine the concentration of Br− ions in the presence of other anions, with a detection limit of 22 nM. 1H NMR studies showed that the imidazolium hydrogen in the Hg(II) complex of receptor N1 participates in the recognition of Br− ions. In the absence of Hg(II), receptor N1 did not recognize Br− ions.en_US
dc.language.isoen_USen_US
dc.subjectFluorescenceen_US
dc.subjectRatiometricen_US
dc.subjectReceptoren_US
dc.subjectRecognitionen_US
dc.subjectBromideen_US
dc.subjectWateren_US
dc.titleSelective detection of Hg(II) with benzothiazole-based fluorescent organic cation and the resultant complex as a ratiometric sensor for bromide in wateren_US
dc.typeArticleen_US
Appears in Collections:Year-2016

Files in This Item:
File Description SizeFormat 
Full Text.pdf1.37 MBAdobe PDFView/Open    Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.