Please use this identifier to cite or link to this item: http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4413
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dc.contributor.authorRoy, S.-
dc.contributor.authorBiswas, A.-
dc.contributor.authorPaul, H.-
dc.contributor.authorAriyan, SK .-
dc.contributor.authorChatterjee, I.-
dc.date.accessioned2024-05-06T07:50:22Z-
dc.date.available2024-05-06T07:50:22Z-
dc.date.issued2024-05-06-
dc.identifier.urihttp://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4413-
dc.description.abstractA rare example of visible-light-mediated diverse reactivity of N-sulfinylamines with different types of carbene precursors has been disclosed. Acylsilanes and aryldiazoacetates have been utilized as nucleophilic and electrophilic carbene precursors into the N�S�O linchpin, to achieve valuable amides and α-iminoesters, respectively. Interestingly, diazocarbonyls can also participate in the amidation reaction with N-sulfinylamines via in situ generated ketenes. This operationally simple modular method offers a mild, transition-metal free, and coupling-reagent-free protocol to fabricate structurally diverse amides and a promptly accessible technique to achieve α-iminoesters, where visible light remains as a key promoter.en_US
dc.language.isoen_USen_US
dc.titleIntroducing N‑Sulfinylamines into Visible-Light-Induced Carbene Chemistry for the Synthesis of Diverse Amides and α‑Iminoestersen_US
dc.typeArticleen_US
Appears in Collections:Year-2023

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