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http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4413
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DC Field | Value | Language |
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dc.contributor.author | Roy, S. | - |
dc.contributor.author | Biswas, A. | - |
dc.contributor.author | Paul, H. | - |
dc.contributor.author | Ariyan, SK . | - |
dc.contributor.author | Chatterjee, I. | - |
dc.date.accessioned | 2024-05-06T07:50:22Z | - |
dc.date.available | 2024-05-06T07:50:22Z | - |
dc.date.issued | 2024-05-06 | - |
dc.identifier.uri | http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4413 | - |
dc.description.abstract | A rare example of visible-light-mediated diverse reactivity of N-sulfinylamines with different types of carbene precursors has been disclosed. Acylsilanes and aryldiazoacetates have been utilized as nucleophilic and electrophilic carbene precursors into the N�S�O linchpin, to achieve valuable amides and α-iminoesters, respectively. Interestingly, diazocarbonyls can also participate in the amidation reaction with N-sulfinylamines via in situ generated ketenes. This operationally simple modular method offers a mild, transition-metal free, and coupling-reagent-free protocol to fabricate structurally diverse amides and a promptly accessible technique to achieve α-iminoesters, where visible light remains as a key promoter. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Introducing N‑Sulfinylamines into Visible-Light-Induced Carbene Chemistry for the Synthesis of Diverse Amides and α‑Iminoesters | en_US |
dc.type | Article | en_US |
Appears in Collections: | Year-2023 |
Files in This Item:
File | Description | Size | Format | |
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full text.pdf | 2.16 MB | Adobe PDF | View/Open Request a copy |
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