Please use this identifier to cite or link to this item: http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4667
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dc.contributor.authorHazra, A.-
dc.contributor.authorDey, R.-
dc.contributor.authorKushwaha, A.-
dc.contributor.authorKumar, T. J. D-
dc.contributor.authorBanerjee, P.-
dc.date.accessioned2024-07-07T07:35:49Z-
dc.date.available2024-07-07T07:35:49Z-
dc.date.issued2024-07-07-
dc.identifier.urihttp://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/4667-
dc.description.abstractAn organocatalytic enantioselective (3 + 3)-cycloaddition reaction of racemic cyclopropane carbaldehydes and aryl hydrazones has been demonstrated for the first time. A wide range of enantioenriched tetrahydropyridazines with an exocyclic double bond were obtained with moderate to good yields and good to excellent enantiomeric excesses. Mechanistic investigations hinted toward a matched/mismatched kinetic resolution, and control experiments and DFT calculations unveiled that 1,3-aryl migration was concerted and intramolecular and proceeds via a four-membered transition state.en_US
dc.language.isoen_USen_US
dc.titleOrganocatalytic Activation of Donor–Acceptor Cyclopropanes: A Tandem (3 + 3)-Cycloaddition/Aryl Migration toward the Synthesis of Enantioenriched Tetrahydropyridazinesen_US
dc.typeArticleen_US
Appears in Collections:Year-2023

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