Please use this identifier to cite or link to this item: http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/570
Title: Synthesis, structure and luminescence property of a 3D diamondoid interpenetrated Zn(II)-Organic framework
Authors: Ugale, B.
Nagaraja, C.M.
Keywords: Zn(II) compound
Metal–organic framework
Interpenetration
Trans, trans-Muconic acid
Luminescence emission
Issue Date: 23-Nov-2016
Abstract: A new metal–organic framework of Zn(II) ion, [Zn(muco)(bipy)2H2O] (where, muco = trans, transmuconate dianion, bipy = 4,40 -bipyridine) has been synthesized by solvothermal reaction of Zn(II) ion, muco ligand and bipy spacer. X-ray structure determination reveals that compound 1 has a 3D diamondoid (dia) framework with novel fivefold interpenetrating nets. Topological analysis shows the presence of 4-connected Zn(II) nodes with {66 } topology. Thermal analysis reveals that the compound is stable up to 340 C. Photoluminescence study shows the emission of 1 owing to the presence of muco ligand and the intensity of luminescence emission is higher than that of free muco ligand.
URI: http://localhost:8080/xmlui/handle/123456789/570
Appears in Collections:Year-2014

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