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http://dspace.iitrpr.ac.in:8080/xmlui/handle/123456789/570| Title: | Synthesis, structure and luminescence property of a 3D diamondoid interpenetrated Zn(II)-Organic framework |
| Authors: | Ugale, B. Nagaraja, C.M. |
| Keywords: | Zn(II) compound Metal–organic framework Interpenetration Trans, trans-Muconic acid Luminescence emission |
| Issue Date: | 23-Nov-2016 |
| Abstract: | A new metal–organic framework of Zn(II) ion, [Zn(muco)(bipy)2H2O] (where, muco = trans, transmuconate dianion, bipy = 4,40 -bipyridine) has been synthesized by solvothermal reaction of Zn(II) ion, muco ligand and bipy spacer. X-ray structure determination reveals that compound 1 has a 3D diamondoid (dia) framework with novel fivefold interpenetrating nets. Topological analysis shows the presence of 4-connected Zn(II) nodes with {66 } topology. Thermal analysis reveals that the compound is stable up to 340 C. Photoluminescence study shows the emission of 1 owing to the presence of muco ligand and the intensity of luminescence emission is higher than that of free muco ligand. |
| URI: | http://localhost:8080/xmlui/handle/123456789/570 |
| Appears in Collections: | Year-2014 |
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