Organic hypervalent iodine(III) catalyzed ipso-hydroxylation of aryl- and alkylboronic acids/esters

dc.contributor.author	Chatterjee, N.
dc.contributor.author	Goswami, A.
dc.date.accessioned	2016-07-28T07:07:45Z
dc.date.available	2016-07-28T07:07:45Z
dc.date.issued	2016-07-28
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/118
dc.description.abstract	An organo-hypervalent iodine(III) catalyzed highly efficient methodology for ipso-hydroxylation of diversely functionalized aryl- and alkylboronic acids/esters has been developed using NaIO4 as a co-oxidant. This protocol is also applicable to N-heterocyclic boronic acids and esters. Further mechanistic studies revealed that the organoboronic acid (an electron demanding moiety) is acting as a nucleophile in the presence of hypervalent iodine for hydroxylation reactions. In summary, this is the first Letter of a generalized route for organic hypervalent iodine(III) catalyzed hydroxylation of organoboronic compounds.	en_US
dc.language.iso	en_US	en_US
dc.subject	Aromatic/aliphatic alcohol	en_US
dc.subject	Hydroxylation	en_US
dc.subject	Hypervalent iodine	en_US
dc.subject	Organoboronic acid	en_US
dc.subject	Organocatalysis	en_US
dc.title	Organic hypervalent iodine(III) catalyzed ipso-hydroxylation of aryl- and alkylboronic acids/esters	en_US
dc.type	Article	en_US