N-Centered radical directed remote C−H bond functionalization via hydrogen atom transfer

Abstract

The N-centeredradicaldirectedremoteCH bondfunctionalizationvia hydrogen-atom-transferat distantsiteshas developedas an enormouspotentialtool for the organicsyntheticchemists.Unactivatedand remotesecondaryandtertiary,as wellas selectedprimaryCH bonds,can be utilizedfor functionalizationby followingthesemethod-ologies.The synthesisof the heterocyclicscaffoldsprovidesthemextraattentionfor the moderndays’developmentsinthis fieldof unactivatedremoteCH bondsfunctionaliza-tions.