Abstract:
The development of green and sustainable transfer hydrogenation protocols without the use of expensive
noble metals and toxic solvents is a challenging task. Herein, a highly stable, low-cost, metal-free heterogeneous
catalyst, oxidized graphitic carbon nitride (O-GCN), has been developed, which exhibits efficient
catalytic hydrogen transfer reactions of carbonyl compounds to corresponding alcohols under mild reaction
conditions. The heterogeneous catalyst was synthesized by the chemical oxidation of graphitic
carbon nitride (GCN) nanosheets, which results in the generation of carboxyl, hydroxyl and ketone groups
over the GCN surface. These hydrophilic groups functionalized on the surface of O-GCN nanosheets act
as catalytically active sites for the hydrogen transfer reactions of carbonyl compounds. A wide range of
substrates was investigated for the hydrogen transfer reactions using 2-propanol both as a hydrogen
donor and a solvent. The O-GCN nanosheets resulted in high yields and high turnover numbers (TON)
demonstrating the versatile catalytic potential of the as-synthesized catalyst. The detailed optimization of
the reaction parameters (temperature, time and catalyst amount) was performed, in addition to the calculation
of green metric parameters. Moreover, the catalyst could be easily recovered and was used for five
runs without any significant loss in catalytic activity. This study provides a green, sustainable, attractive,
and useful methodology for the hydrogen transfer reactions of a wide range of carbonyl compounds.
