Abstract:
In this study, a novel processing technique for microstructural refinement of Ni-Cr-5Al2O3 composite coating
developed using high velocity oxy-fuel (HVOF) technique is demonstrated. The processing technique, known as
stationary friction processing (SFP) is an adaptation of the well-known friction stir processing (FSP). The assprayed
coating showed a typical lamellar microstructure along with non-homogeneous elemental distribution.
The SFP treatment resulted in significant microstructural refinement with complete elimination of splat
boundaries and pores together with fully homogeneous elemental distribution. The performance of as-sprayed
and processed coatings was evaluated in slurry erosion, erosion-corrosion and pure corrosion in 3.5% NaCl
solution. At oblique impingement angle, the SFP treated sample showed minimum erosion rate of nearly
0.1 mm3/h which is 3–5 times lower than the as-sprayed coating and the substrate. For normal impingement, the
erosion rate of SFP specimen was nearly 30% lower compared to the as-sprayed coating and the substrate. This is
attributed to higher hardness as well as fracture toughness of the SFP treated coating as a result of microstructural
refinement. In addition, the SFP treated coating was able to demonstrate superior resistance under
erosion-corrosion conditions as well. Further, the processed sample showed lowest corrosion rate of 0.079 μA/
cm2, 5–6 times lower than the as-sprayed coating (0.39 μA/cm2). The enhancement in the corrosion resistance of
the coating after processing is attributed to complete homogenization of the coating with removal of all splats,
splat boundaries, pores and regions of elemental segregation.
