Chemoselective RuII-Catalyzed synthesis of aryl thiocyanates and Step-wise double [2+2+2] cycloadditions to 2-Aryl thiopyridines

dc.contributor.author	Bhatt, D.
dc.contributor.author	Kalaramna, P.
dc.contributor.author	Kumar, K.
dc.contributor.author	Goswami, A.
dc.date.accessioned	2021-06-30T23:17:50Z
dc.date.available	2021-06-30T23:17:50Z
dc.date.issued	2021-07-01
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/1941
dc.description.abstract	An atom-economical approach towards the synthesis of aryl thiocyanates has been documented employing ruthenium-catalyzed [2+2+2] cycloaddition strategy. Sequential RuII-catalyzed intermolecular [2+2+2] cycloadditions of 1,6-diynes and formed aryl thiocyanates resulted in the synthesis of 2-aryl thiopyridines. RuII-catalyzed intermolecular double [2+2+2] cycloadditions of 1,6-diynes and alkynylthiocyanates have been developed for the synthesis of 2-aryl thiopyridines. Aryl thiocyanates were isolated chemoselectively as a result of initial intermolecular [2+2+2] cycloaddition product. The method offers operational simplicity and is atom economical in nature.	en_US
dc.language.iso	en_US	en_US
dc.title	Chemoselective RuII-Catalyzed synthesis of aryl thiocyanates and Step-wise double [2+2+2] cycloadditions to 2-Aryl thiopyridines	en_US
dc.type	Article	en_US