Abstract:
The hydrogenation of CO2 to methanol over Cu-nanoparticles supported on TiO2 nanocrystals was studied at 30
bar pressure and 200− 300 ◦C. 5 wt% Cu-TiO2 catalyst was synthesized by a modified hydrothermal method (CuTiO2
HT) and by incipient wetness impregnation method (Cu-TiO2
IMP). TEM analysis of the Cu-TiO2
HT catalyst
revealed the formation of Cu-nanoparticles (3-5 nm), while larger Cu particle sizes were observed on the CuTiO2
IMP catalyst. The Cu-TiO2
HT catalyst showed superior catalytic activity (CO2 conversion ~ 9.4 %) and methanol selectivity (~ 96 %) at 200 ◦C and 30 bar pressure. Low CO2 conversions (~6%) and high CO selectivity
(~40 %) was obtained on the Cu-TiO2
IMP catalyst. Density functional theory (DFT) calculations indicated the CO2
activation to methanol to proceed via a reverse water gas shift pathway with a significantly lower (93 kJ/mol)
CO2 activation barrier on the Cu-nanoparticles, relative to the larger Cu particles (127 kJ/mol). In addition, the
higher selectivity towards methanol over the Cu-TiO2
HT catalyst was attributed to the higher CO and HCO stability on the Cu nanoparticles. Time of stream (TOS) study of the Cu-TiO2 catalysts showed no significant
deactivation even after 150 h with molar feed ratio 1:3:1 (CO2:H2: N2) at 200 ◦C.
