Abstract:
The development of cost-effective heterogeneous catalysts for the selective conversion of biomassderived platform chemicals into value-added chemicals and liquid fuels will pave the way towards the
development of sustainable biorefineries. Herein, we perform in-depth optimization of the catalyst
composition and experimental conditions to selectively produce three important value-added chemicals
from furfural, including cyclopentanone, furfuryl alcohol, and tetrahydrofurfuryl alcohol. Results show
that the Ni(10%)/CuFe2O4 catalyst affords cyclopentanone as a major product with >90% selectivity in
water at 423 K and 1 MPa H2. Meanwhile, switching to non-aqueous solvents, including hexane,
isopropanol, toluene, and ethanol, selectively produces tetrahydrofurfuryl alcohol as a major product
under identical reaction conditions. Over the Cu(10%)/CuFe2O4 catalyst, furfuryl alcohol is produced as
a major product in water at 393 K and 1 MPa H2. Control experiments over M/CuO, M/Fe3O4, and M/
SBA-15 catalysts are also performed; however. these catalysts afford much lower conversion compared
to the M/CuFe2O4 catalysts due to the higher Lewis acidity of the CuFe2O4 support. The
physicochemical properties of these catalysts are characterized using powder XRD, HR-TEM, XPS, and
pyridine FT-IR. Finally, based on the existing literature, plausible reaction mechanisms for the production
of cyclopentanone, tetrahydrofurfuryl alcohol, and furfural alcohol on M/CuFe2O4 catalysts are
proposed. The present work provides insight into the development of cost-effective and efficient
catalysts for the valorization of furfural under mild conditions.
