INSTITUTIONAL DIGITAL REPOSITORY

Poly(ionic liquid)-zinc polyoxometalate composite as a binder-free cathode for high-performance lithium-sulfur batteries

Show simple item record

dc.contributor.author Singh, V.
dc.contributor.author Padhan, A. K.
dc.contributor.author Adhikary, S. S.
dc.contributor.author Tiwari, A.
dc.contributor.author Mandal, D.
dc.contributor.author Nagaiah, T. C.
dc.date.accessioned 2021-08-31T23:17:29Z
dc.date.available 2021-08-31T23:17:29Z
dc.date.issued 2021-09-01
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/2597
dc.description.abstract The development of the most promising next-generation Li–S batteries with high utilization of sulfur while retaining high capacity is one of the great challenges of the 21st century. Here, we reported sandwich polyoxometalate [WZn3(H2O)2(ZnW9O34)2] 12 (ZnPOM) over a poly(1-vinyl-3(2-(2-methoxyethoxy)ethyl)imidazolium) cation (PVIMo) matrix as a binder-free cathode catalyst for a high-capacity LiS battery with a high areal loading of 7.68 mg cm 2 and high areal capacity of 11.14 mA h cm 2 (70% sulfur). The synergistic effect between PVIMo and ZnPOM resulted in outstanding initial discharge capacity of 1450 mA h g 1 at 0.5 C with high capacity retention (97%), high coulombic efficiency (>98%) and a negligible capacity fading rate of 0.02% per cycle at an electrolyte/sulfur ratio of 10 mL(E) mg(S) 1 and capacity fading of only 0.02% per cycle. The cationic polymer PVIMo held the negatively charged polysulfide ions at the cathode and ZnPOM facilitated the conversion of polysulfides to sulfur. Quantitative estimation by EQCM, UV-Vis analysis and potentiometric titration demonstrated negligible loss of sulfur even after 120 cycles of the charge–discharge process. en_US
dc.language.iso en_US en_US
dc.title Poly(ionic liquid)-zinc polyoxometalate composite as a binder-free cathode for high-performance lithium-sulfur batteries en_US
dc.type Article en_US


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse

My Account