INSTITUTIONAL DIGITAL REPOSITORY

Influence of -SO 3H functionalization (N-SO 3H or N-R-SO 3H, where R = alkyl/benzyl) on the activity of brönsted acidic ionic liquids in the hydration reaction

Show simple item record

dc.contributor.author Kore, R.
dc.contributor.author Srivastava, R.
dc.date.accessioned 2021-09-18T11:52:07Z
dc.date.available 2021-09-18T11:52:07Z
dc.date.issued 2021-09-18
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/2698
dc.description.abstract Sulfonic acid group functionalized imidazole based Brönsted acidic ionic liquids (BAILs) were synthesized and their activities were investigated in the hydration reaction of alkynes. The Hammett acidity order determined from UV–visible spectroscopy of BAILs is consistent with their activity order observed in hydration reactions. Theoretical studies further help to establish the structure–activity relationship. Recycling experiments suggest that these novel BAILs can be reused without significant loss in activity. Applicability of BAILs in hydration reaction opens a non-toxic, economical, and eco-friendly route to synthesize alkyl ketones from alkynes. en_US
dc.language.iso en_US en_US
dc.subject Brönsted acidic ionic liquids en_US
dc.subject Hydration reaction en_US
dc.subject DFT calculations en_US
dc.subject Hammett acidity en_US
dc.title Influence of -SO 3H functionalization (N-SO 3H or N-R-SO 3H, where R = alkyl/benzyl) on the activity of brönsted acidic ionic liquids in the hydration reaction en_US
dc.type Article en_US


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse

My Account