Electricity driven 1,3-Oxohydroxylation of Donor-Acceptor cyclopropanes: a mild and straightforward access to β-Hydroxy ketones

dc.contributor.author	Saha, D.
dc.contributor.author	Taily, I. M.
dc.contributor.author	Banerjee, P.
dc.date.accessioned	2021-11-15T11:19:00Z
dc.date.available	2021-11-15T11:19:00Z
dc.date.issued	2021-11-15
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/3170
dc.description.abstract	An unprecedented external oxidant-free electrochemical protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropane is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp 3 Csp 3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of molecular oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed	en_US
dc.language.iso	en_US	en_US
dc.title	Electricity driven 1,3-Oxohydroxylation of Donor-Acceptor cyclopropanes: a mild and straightforward access to β-Hydroxy ketones	en_US
dc.type	Article	en_US