Photoinduced diverse reactivity of diazo compounds with nitrosoarenes

dc.contributor.author	Roy, S.
dc.contributor.author	Kumar, G.
dc.contributor.author	Chatterjee, I.
dc.date.accessioned	2021-11-15T12:27:11Z
dc.date.available	2021-11-15T12:27:11Z
dc.date.issued	2021-11-15
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/3177
dc.description.abstract	A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal [2 + 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen source to oxidize an in situ generated carbene intermediate under visible-light irradiation. UV-light-mediated in situ generated ketenes react with nitosoarenes to deliver oxazetidine derivatives. These operationally simple processes exemplify a transition-metal-free and catalyst-free protocol to give structurally diverse α-ketoesters or oxazetidines.	en_US
dc.language.iso	en_US	en_US
dc.title	Photoinduced diverse reactivity of diazo compounds with nitrosoarenes	en_US
dc.type	Article	en_US