Nitrosoarene-Catalyzed HFIP-Assisted transformation of arylmethyl halides to aromatic carbonyls under aerobic conditions

dc.contributor.author	Pradhan, S.
dc.contributor.author	Sharma, V.
dc.contributor.author	Chatterjee, I.
dc.date.accessioned	2021-11-16T19:16:22Z
dc.date.available	2021-11-16T19:16:22Z
dc.date.issued	2021-11-17
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/3194
dc.description.abstract	A rare metal-free nucleophilic nitrosoarene catalysis accompanied by highly hydrogen-bond-donor (HBD) solvent, 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), organocatalytically converts arylmethyl halides to aromatic carbonyls. This protocol offers an effective means to access a diverse array of aromatic carbonyls with good chemoselectivity under mild reaction conditions. The activation of arylmethyl halides by HFIP to generate stable carbocation and autoxidation of in situ generated hydroxylamine to nitrosoarene in the presence of atmospheric O2 are the keys to success.	en_US
dc.language.iso	en_US	en_US
dc.title	Nitrosoarene-Catalyzed HFIP-Assisted transformation of arylmethyl halides to aromatic carbonyls under aerobic conditions	en_US
dc.type	Article	en_US