Redox-active alkylsulfones as precursors for alkyl radicals under photoredox catalysis

dc.contributor.author	Patel, S.
dc.contributor.author	Paul, B.
dc.contributor.author	Paul, H.
dc.contributor.author	Shankhdhar, R.
dc.contributor.author	Chatterjee, I.
dc.date.accessioned	2022-05-31T20:05:17Z
dc.date.available	2022-05-31T20:05:17Z
dc.date.issued	2022-06-01
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/3470
dc.description.abstract	A method for generating alkyl radicals using visible-light photoredox catalysis is described. This procedure was found to present an efficient means to access a diverse collection of 1°, 2°, and 3° alkyl radicals through the single-electron transfer of sulfones under mild reaction conditions. These alkyl radicals generated via the reductive desulfonylation of readily synthesized and stable alkylsulfones were engaged to forge C-C bonds. A detailed study was also carried out to shed light on the mechanism.	en_US
dc.language.iso	en_US	en_US
dc.title	Redox-active alkylsulfones as precursors for alkyl radicals under photoredox catalysis	en_US
dc.type	Article	en_US