Polymer-based self-assembled photonic crystals to tune light transport and emission

Abstract

The advent of photonic crystals has made possible the idea of controlling flows of light, which has revolutionized photonics-based technology. Photonic crystals are constructed based on periodic refractive index variations in one-, two-, or three-spatial dimensions on the optical-wavelength scale. Photonic crystals show inherent photonic stop gaps or band gaps depending upon the crystal symmetry and refractive index contrast. Showing ease of fabrication, polymer-based self-assembled photonic crystals with stop gaps have been widely explored. We discuss angle- and polarization-dependent stop gap creation and splitting at higher angles of incidence. The observed stop gaps in self-assembled photonic crystals often deviate from theoretical predictions due to experimental constraints, such as finite size and fabrication disorders associated with samples. We perform micro-reflectivity experiments on a single domain, showing minimal disorder, with nearly 100% reflectivity, which is in agreement with theory. We obtain more than 75% emission intensity suppression and a 30% increase in the emission lifetime at the stop gap using micro-emission experiments in a single domain. This enables us to study the role of finite-size effects in photonic crystals in modifying the emission properties. We observe the linear scaling of the emission intensity suppression and the emission rate with the finite size of the crystal. Our single-domain experimental studies reveal that the use of low index-contrast self-assembled photonic crystals is a potential platform for strategically modifying light transport and emission properties.