Temperature-controlled chemoselective synthesis of thiosulfonates and thiocyanates: Novel reactivity of KXCN (X=S, Se) towards organosulfonyl chlorides

dc.contributor.author	Kalaramna, P.
dc.contributor.author	Goswami, A.
dc.date.accessioned	2022-08-21T09:42:03Z
dc.date.available	2022-08-21T09:42:03Z
dc.date.issued	2022-08-21
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/3847
dc.description.abstract	An efficient chemoselective protocol has been developed for the synthesis of thiosulfonates and thiocyanates by employing cost effective and commercially available organosulfonyl chlorides with potassium thio-/selenocyanate. The strategy offered the thiosulfonates and thiocyanates selectively by tuning the equivalents of KSeCN and optimizing the reaction temperature. On the other hand, thiosulfonates were obtained as sole products when organosulfonyl chlorides were treated with KSCN. Furthermore, the syntheses of diarylthioethers and aryl(heteroaryl) thioethers were carried out as a part of synthetic application of newly prepared arylthiocyanates.	en_US
dc.language.iso	en_US	en_US
dc.subject	Organosulfonyl chlorides	en_US
dc.subject	Selenocyanates	en_US
dc.subject	Thiocyanates	en_US
dc.subject	Thioethers	en_US
dc.subject	Thiosulfonates	en_US
dc.title	Temperature-controlled chemoselective synthesis of thiosulfonates and thiocyanates: Novel reactivity of KXCN (X=S, Se) towards organosulfonyl chlorides	en_US
dc.type	Article	en_US