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An Atom-Economical Approach to 2-Triazolyl Thio-/Seleno Pyridines via Ruthenium-Catalyzed One-pot [3+2]/[2+2+2] Cycloadditions

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dc.contributor.author Bhatt, D.
dc.contributor.author Singh, P.R.
dc.contributor.author Kalaramna, P.
dc.contributor.author Kumar, K.
dc.contributor.author Goswami, A.
dc.date.accessioned 2022-08-23T10:42:18Z
dc.date.available 2022-08-23T10:42:18Z
dc.date.issued 2022-08-23
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/3868
dc.description.abstract An efficient method to access 2-triazolyl thio-/selenopyridines with good to excellent yields by ruthenium(II)-catalyzed one-pot [3+2]/[2+2+2] cycloaddition reactions of azides, 1-alkynyl thio-/selenocyanates and 1,6-diynes is reported. This atom-economical catalytic strategy offers a mild and practical approach to access a variety of such cycloadducts with good to excellect regioselectivities. The protocol was further extended to the synthesis of 3,3′-bis(triazolyl thio-/seleno)-2,2′-bipyridines by the reaction of tetraynes with 1-alkynyl thio-/selenocyanates in the presence of aryl/alkyl azides en_US
dc.language.iso en_US en_US
dc.subject cyclotrimerizations en_US
dc.subject ruthenium catalysis en_US
dc.subject Thio-/seleno substituted triazoles en_US
dc.subject triazolyl thio-/selenopyridines en_US
dc.subject [3+2] cycloadditions en_US
dc.title An Atom-Economical Approach to 2-Triazolyl Thio-/Seleno Pyridines via Ruthenium-Catalyzed One-pot [3+2]/[2+2+2] Cycloadditions en_US
dc.type Article en_US


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