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Fluorescent chemosensor for Al3 + and resultant complex as a chemosensor for perchlorate anion: First molecular security keypad lock based on Al3 + and ClO4− inputs

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dc.contributor.author Kaur, K.
dc.contributor.author Bhardwaj, V.K.
dc.contributor.author Kaur, N.
dc.contributor.author Singh, N.
dc.date.accessioned 2016-05-16T09:18:06Z
dc.date.available 2016-05-16T09:18:06Z
dc.date.issued 2016-05-16
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/40
dc.description.abstract A dipodal sensor detects Al3 + in HEPES buffered THF/H2O (7:3, v/v) through excited state proton transfer, representing a quenching at 355 nm and enhancement at 480 nm. The resulting aluminium complex (1.Al3 +) displays a highly selective response to perchlorate anion over other anions through the emergence of a new band at 428 nm. The chemical inputs of Al3 + and ClO4− satisfies the conditions of AND molecular logic gates and in a sequential manner generates an output which mimics the functions of a security keypad lock. en_US
dc.language.iso en_US en_US
dc.subject Chemosensor en_US
dc.subject Recognition en_US
dc.subject Host–guest Chemistry en_US
dc.subject Dipodal Receptor en_US
dc.subject Al3 + en_US
dc.title Fluorescent chemosensor for Al3 + and resultant complex as a chemosensor for perchlorate anion: First molecular security keypad lock based on Al3 + and ClO4− inputs en_US
dc.type Article en_US


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