INSTITUTIONAL DIGITAL REPOSITORY

Fluorescence chemosensor for HSO4 − Ion based on pyrrole-substituted salicylimine Zn2+ complex: Nanomolar detection

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dc.contributor.author Fegade, U.
dc.contributor.author Bhosale, J.
dc.contributor.author Sharma, H.
dc.contributor.author Singh, N.
dc.contributor.author Bendre, R.
dc.contributor.author Kuwar, A.
dc.date.accessioned 2016-11-18T06:27:17Z
dc.date.available 2016-11-18T06:27:17Z
dc.date.issued 2016-11-18
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/418
dc.description.abstract A novel pyrrole-substituted salicylimine zinc (II) ion complex has been synthesized and evaluated its anion binding affinity. The probe 4 has high selectivity for HSO4 − over other anions in CH3OH:H2O (70:30, v/v) solvent system. The emission intensity of 4 was quenched upon addition of HSO4 − . The probe 4 is highly selective for HSO4 − with a detection limit of 40 nm. Photoinduced electron transfer (PET) is responsible for observed change. The binding affinity of 4 for HSO4 − was further authenticated through ratiometric change in absorbance profile. en_US
dc.language.iso en_US en_US
dc.subject Pyrrole-substituted salicylimine en_US
dc.subject HSO4 en_US
dc.subject Ratiometric en_US
dc.subject Quenching en_US
dc.title Fluorescence chemosensor for HSO4 − Ion based on pyrrole-substituted salicylimine Zn2+ complex: Nanomolar detection en_US
dc.type Article en_US


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