Unveiling two antiaromatic s-indacenodicarbazole isomers with tunable paratropicity

dc.contributor.author	Saha, H.K.
dc.contributor.author	Mallick, D.
dc.contributor.author	Das, S.
dc.date.accessioned	2022-11-25T07:32:15Z
dc.date.available	2022-11-25T07:32:15Z
dc.date.issued	2022-11-25
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/4251
dc.description.abstract	Linear and curved antiaromatic s-indacenodicarbazole isomers were synthesized and characterized to show the tunable paratropicity of s-indacene, as analyzed by NICS(1)zz and ACID (ring-current) calculations. The curved isomer showed a greater degree of antiaromaticity than the linear isomer, as predicted by the Glidewell-Lloyd rule. This degree of antiaromaticity was further validated by the red-shifted UV-vis absorption and smaller HOMO-LUMO energy gap.	en_US
dc.language.iso	en_US	en_US
dc.title	Unveiling two antiaromatic s-indacenodicarbazole isomers with tunable paratropicity	en_US
dc.type	Article	en_US