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Lewis-Acid-Catalysed tandem meinwald rearrangement/Intermolecular [3+2]- Cycloaddition of epoxides with Donor–acceptor cyclopropanes: Synthesis of functionalized tetrahydrofurans

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dc.contributor.author Pandey, A.K.
dc.contributor.author Ghosh, A.
dc.contributor.author Banerjee, P.
dc.date.accessioned 2016-11-19T06:46:43Z
dc.date.available 2016-11-19T06:46:43Z
dc.date.issued 2016-11-19
dc.identifier.uri http://localhost:8080/xmlui/handle/123456789/482
dc.description.abstract A Lewis-acid-catalysed tandem Meinwald rearrangement/[3+2]-cycloaddition of epoxides with donor-acceptor cyclopropanes to synthesize varieties of cis-2,5-aryl-benzyl-substituted tetrahydrofurans is described. An enantioselective version of the same transformation was achieved using an InCl3-PyBOX catalyst system. A Lewis-acid-catalysed tandem Meinwald rearrangement/[3+2]-cycloaddition of epoxides with donor-acceptor cyclopropanes to synthesize varieties of cis-2,5-aryl-benzyl-substituted tetrahydrofurans is described. An enantioselective version of the same transformation is also presented using various BOX ligands. en_US
dc.language.iso en_US en_US
dc.subject Asymmetric synthesis en_US
dc.subject Cyclization en_US
dc.subject Oxygen heterocycles en_US
dc.subject Small ring systems en_US
dc.subject Epoxides en_US
dc.title Lewis-Acid-Catalysed tandem meinwald rearrangement/Intermolecular [3+2]- Cycloaddition of epoxides with Donor–acceptor cyclopropanes: Synthesis of functionalized tetrahydrofurans en_US
dc.type Article en_US


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