Synthesis, structure and luminescence property of a 3D diamondoid interpenetrated Zn(II)-Organic framework

dc.contributor.author	Ugale, B.
dc.contributor.author	Nagaraja, C.M.
dc.date.accessioned	2016-11-23T04:42:05Z
dc.date.available	2016-11-23T04:42:05Z
dc.date.issued	2016-11-23
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/570
dc.description.abstract	A new metal–organic framework of Zn(II) ion, [Zn(muco)(bipy)2H2O] (where, muco = trans, transmuconate dianion, bipy = 4,40 -bipyridine) has been synthesized by solvothermal reaction of Zn(II) ion, muco ligand and bipy spacer. X-ray structure determination reveals that compound 1 has a 3D diamondoid (dia) framework with novel fivefold interpenetrating nets. Topological analysis shows the presence of 4-connected Zn(II) nodes with {66 } topology. Thermal analysis reveals that the compound is stable up to 340 C. Photoluminescence study shows the emission of 1 owing to the presence of muco ligand and the intensity of luminescence emission is higher than that of free muco ligand.	en_US
dc.language.iso	en_US	en_US
dc.subject	Zn(II) compound	en_US
dc.subject	Metal–organic framework	en_US
dc.subject	Interpenetration	en_US
dc.subject	Trans, trans-Muconic acid	en_US
dc.subject	Luminescence emission	en_US
dc.title	Synthesis, structure and luminescence property of a 3D diamondoid interpenetrated Zn(II)-Organic framework	en_US
dc.type	Article	en_US