A highly selective and sensitive fluorescent ‘turn-on’ chemosensor for Al3+ based on Cdouble bond; length as m-dashN isomerisation mechanism with nanomolar detection

dc.contributor.author	Torawane, P.
dc.contributor.author	Tayade, K.
dc.contributor.author	Bothra, S.
dc.contributor.author	Sahoo, S.K.
dc.contributor.author	Singh, N.
dc.contributor.author	Borse, A.
dc.contributor.author	Kuwar, A.
dc.date.accessioned	2016-07-19T10:47:19Z
dc.date.available	2016-07-19T10:47:19Z
dc.date.issued	2016-07-19
dc.identifier.uri	http://localhost:8080/xmlui/handle/123456789/82
dc.description.abstract	A new Schiff base 1 was synthesised by direct condensation of 4-tert-butyl-2-aminophenol with an equimolar amount of 4-(diethylamino)-2-hydroxybenzaldehyde and characterised by single crystal XRD. The chemosensing ability of 1 in ethanol was evaluated towards various metal ions prepared in H2O. Sensor 1 showed a high sensitivity and selectivity for Al3+ through a significant ‘turn-on’ fluorescence response at 490 nm over the other tested metal ions with a detection limit down to 99.5 nM. The 1:1 binding stoichiometry between 1 and Al3+ was established using Job's plot, and the proposed complex structure was calculated by applying the DFT method.	en_US
dc.language.iso	en_US	en_US
dc.subject	Fluorescent sensor	en_US
dc.subject	Al3+	en_US
dc.subject	Turn-on	en_US
dc.subject	Cdouble bond; length as m-dashN isomerisation	en_US
dc.subject	DFT	en_US
dc.title	A highly selective and sensitive fluorescent ‘turn-on’ chemosensor for Al3+ based on Cdouble bond; length as m-dashN isomerisation mechanism with nanomolar detection	en_US
dc.type	Article	en_US